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Lesson 1. Is Matter Around Us Pure?

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Pure Substances

Compounds

Compounds are the substances consisting of two or more different types of elements in a fixed ratio of its atoms.

Difference between Mixtures and Compounds

Compound Mixture
Compounds are substances which can be formed by chemically combining two or more elements. Mixtures are substances that are formed by physically mixing two or more substances.
Compounds fall under pure substances. Mixtures can be categorized as impure substances.
The chemical composition of compounds is always fixed. A mixture can have a variable composition of the substances forming it.
Compounds are always homogeneous in nature. Mixtures can either be homogeneous or heterogeneous in nature.
A new substance is formed after the constituents are chemically combined. So, a compound has different properties from its constituents. No new substances are formed in mixtures and their properties are dependent on the properties of their respective constituents.

Example of compounds includes water (H2O), Hydrogen Peroxide (H2O2), etc. You can see water’s chemical formula, it says it has 2 atoms of Hydrogen combined with 1 atom of oxygen and in hydrogen peroxide, it has 2 atoms of hydrogen and two atoms of oxygen.

Elements

Metals

Nonmetals

Pure Elements and Compounds

Category Examples
Pure Elements - Iron (Fe)
- Oxygen (O₂)
- Gold (Au)
- Copper (Cu)
- Carbon (C)
- Nitrogen (N₂)
- Helium (He)
- Aluminum (Al)
Pure Compounds - Water (H₂O)
- Sodium chloride (NaCl)
- Carbon dioxide (CO₂)
- Methane (CH₄)
- Sulfur dioxide (SO₂)
- Calcium carbonate (CaCO₃)
- Hydrochloric acid (HCl)

Key Points:

Metalloids

Mixtures

A mixture in chemistry is a substance made up of two or more unrelated chemical components. A mixture is a physical combination of two or more distinct substances that can take the form of solutions, suspensions, or colloids.

Mixtures are formed by just mixing two or more pure substances (components) such that each substance retains its own chemical identity.

Types of Mixtures:

Heterogeneous and homogeneous mixtures are the two types of mixtures. While homogeneous mixtures seem consistent throughout, heterogeneous mixtures have clearly discernible components. A solution, which can be a solid, liquid, or gas, is the most typical kind of homogenous mixture.

1. Homogeneous Mixture

A mixture which has a uniform composition throughout is called a homogeneous mixture or solution.

Heterogeneous Mixture

A mixture which contains physically distinct parts and has a non-uniform composition is called a heterogeneous mixture. Examples: Mixture of salt and iron filings, sand and sugar.

Physical vs Chemical Changes

The nature of the substance, the particles that make up it, and the quantity of particles all stay unaltered after a physical change. Chemical changes result in new compounds with different properties from the original ones, as well as new particles and maybe altered particle numbers.

Physical and Chemical Changes

Solutions and Their Properties

 Properties

Alloys

Alloys are homogeneous mixtures of metals or a mixture of a metal and another element that cannot be separated into their components by physical methods.
Examples:

Concentration of Solutions

The amount of solute that has dissolved in a specific amount of solvent or solution is measured as solution concentration. A concentrated solution is one that has a significant amount of dissolved solute in it. A diluted solution is one that has a small amount of dissolved solute in it.

Solubility

Unsaturated solutions, on the other hand, are those that contain less solute than the maximum that can be dissolved. A saturated solution is one that contains the maximum quantity of solute that can be dissolved. The amount of a solute that dissolves in a solvent is known as its solubility. The majority of solutes become more soluble when the solvent’s temperature rises.

Factors Affecting Solubility: 

Types of Solutions based on the Concentration of the Solution

There are 2 main types of solutions based on the definition. A dilute Solution is a solution that contains a small amount of solute. A concentrated Solution is a solution that contains a lot of solutes. Three types of solutions exist based on the concentration of the solution:

  1. Dilute
  2. Concentrated
  3. Saturated solution.

Ways of Representing the Concentration of a Solution

The concentration of a solution can be represented in many ways

(i) Mass by the mass percentage of a solution = (Mass of solute / Mass of solution) × 100

(ii) Mass by volume percentage of a solution = (Mass of solute/ volume of solution)×100

For example, if a solution of NaCl in water is said to be 10 % by volume that means a 100 ml solution will contain 10 ml NaCl.

Suspensions

Suspension and Its Properties

suspension is a heterogeneous mixture in which the solute particles do not dissolve but remain suspended throughout the bulk of the medium.

Colloids

Types of Mixtures based on Particle Size

Classified into:

Colloidal Solutions

colloidal solution is a mixture in which the substances are regularly suspended in a fluid.

Properties of colloids and their variation are a well-known area ever since the primitive age. The best example to prove their familiarity with us is that we know from very early times that coagulation of milk results in the formation of curd.

Tyndall Effect

Tyndall effect is the scattering of light by particles in a colloid or else particles in a very fine suspension.

Dispersed Phase

The solute-like component of the dispersed particles in a colloid form the dispersed phase.

Dispersion Medium

The component in which the dispersed phase is suspended is known as the dispersing medium.

Aerosol

A colloidal solution with dispersed phase solid/liquid and dispersing medium gas is called Aerosol. e.g. clouds

Foam

A colloidal solution with dispersed phase gas and dispersing medium solid/liquid is called Foam. e.g.Shaving cream.

Sols

A colloidal solution with dispersed phase solid and dispersing medium liquid is called Sol. e.g. Milk of magnesia, mud.

Gels and Emulsions

Emulsion and gel are two distinct chemical compounds. A gel is a semisolid substance, but an emulsion is a liquid, which is the main distinction between the two. Nevertheless, depending on their intended use, some emulsions can exist in a semisolid condition. Fruit jellies, a gelatinous substance, creams, etc.

Evaporation

The process of conversion of water into water vapour is known as evaporation.

Examples: Clothes drying in the sun. Tea and other hot liquids are cooled down. Dry Floors
Ice cubes melting.

Separation of Components of a Mixture

Separation of a Mixture of Two Immiscible Liquids

Immiscible liquids break out into layers according to their densities, which is the basic idea behind the separation of immiscible liquids using a separating funnel.

Centrifugation

Applications

Sublimation

Sublimation is the transition of a substance from solid phase to gaseous phase without changing into liquid phase.

Solid undergoing sublimation

Chromatography

Applications

Distillation

Distillation is a method for separating the component substances from a liquid mixture by selective evaporation and condensation.

Fractional Distillation

Fractional Distillation is the separation of a mixture into its component parts or fractions by their melting points.

Separation of Air into Its Components

Process of Obtaining Different Gases from the Air

Air is a homogeneous mixture and can be separated into its components by fractional distillation.

Mixtures are substances made up of two or more different kinds of material. Homogeneous and heterogeneous mixtures are the two types of mixtures. There is no particle level homogeneity and the components in a heterogeneous mixture are not dispersed uniformly. As a result, we may simply divide a heterogeneous mixture into its various components.

A few popular separation methods for the heterogeneous mixture include sieving, filtration, hand-picking, etc. We must employ specialised separation procedures when dealing with homogeneous mixtures, as well as occasionally heterogeneous mixtures. Special separation techniques include evaporation, centrifugation, chromatography, sublimation, separating funnels, etc.

Fractional distillation

Crystallization

Crystallisation is better than evaporation because during evaporation, some solids decompose or some, like sugar, may get charred on heating to dryness. Some impurities may remain dissolved in the solution even after filtration which on evaporation contaminates the solid.

Applications of Crystallisation

Purification of seawater, separation of alum crystals from impure samples etc.

Textbook Solutions

  1. What is meant by a substance?

,A substance is a pure single form of matter. It has definite properties and compositions. Example: Iron

  1. List the points of difference between homogeneous and heterogeneous mixtures.

Answer:

Difference between Homogeneous and Heterogeneous Mixtures

Homogeneous Mixture Heterogeneous Mixture
Particles are uniformly distributed throughout the mixture. Particles are not uniformly distributed and can be distinguished with the naked eye or microscope.
Has a uniform composition. Irregular composition.
No apparent boundaries of separation. Noticeable boundaries of separation.

Exercise 2.2 – Page 18

Difference between Homogeneous and Heterogeneous Mixtures

Homogeneous Mixture Heterogeneous Mixture
Particles are uniformly distributed throughout the mixture. Particles are not uniformly distributed and can be distinguished with the naked eye or microscope.
Has a uniform composition. Irregular composition.
No apparent boundaries of separation. Noticeable boundaries of separation.

Exercise 2.2 – Page 18

  1. Differentiate between homogeneous and heterogeneous mixtures with examples.

Answer: The following are the differences between heterogeneous and homogeneous mixtures:

Heterogeneous Mixture Homogeneous Mixture
Particles can be seen and separated easily with the naked eye or under a microscope. Particles are uniformly distributed and not visible separately.
Irregular composition. Uniform composition.
Noticeable boundaries of separation. No visible boundaries.
Examples: Seawater, blood, sand in water. Examples: Saltwater, vinegar, air.
  1. How are sol, solution, and suspension different from each other?

Answer:

Attributes Sol Solution Suspension
Type of mixture Heterogeneous Homogeneous Heterogeneous
Size of particles 10⁻⁷ – 10⁻⁵ cm Less than 1 nm More than 100 nm
Tyndall effect Exhibited Not exhibited May or may not be exhibited
Appearance Glassy and clear Unclouded and clear Cloudy and opaque
Visibility Visible with ultramicroscope Not visible Visible with naked eye
Diffusion Diffuses slowly Diffuses rapidly Does not diffuse
Stability Stable Highly stable Unstable
Settling Settle during centrifugation Do not settle Settle on their own
Examples Milk, blood, smoke Salt solution, sugar in water Sand in water, dusty air
  • To make a saturated solution , 36 g of sodium chloride is dissolved in 100 g of water at 293 K. Find its concentration at this temperature.
  • Answer:

    Mass of solute (NaCl) = 36 g

    Mass of solvent (H2O) = 100 g

    Mass of , (NaCl + H2O) = 136 g

    Concentration = Mass of solute/Mass of solvent, x 100

    Concentration = 36/136 x 100 = 26.47%

    Hence, the concentration of the , is 26.47%

    Exercise-2.3 Page: 24

    1. How will you separate a mixture containing kerosene and petrol (the difference in their boiling points is more than 25°C), which are miscible with each other?

    According to the question, kerosene and petrol are miscible, and their boiling points differ by more than 25 degrees Celsius, which is a significant difference. Therefore they can be separated using a simple distillation procedure.

    Distillation can separate kerosene and petrol since their boiling points differ by more than 25 degrees Celsius. The kerosene and petrol combination will be poured into a hot distillation flask. Because petrol has a lower boiling point, it will evaporate and create vapours first as the temperature of the mixture rises. A condenser condenses the vapours of gasoline and collects them through the condenser output. In the distillation flask, kerosene with a higher boiling point will be left behind.

    Because their vapours will develop within the same temperature range if the difference in boiling points of two liquids is not great, a simple distillation procedure cannot be utilised to separate them. Fractional distillation separates these liquids by passing the vapours through a fractionating column before condensation.

    1. Name the techniques used to separate the following:

    (a) Butter from curd

    (b) Salt from seawater

    (c) Camphor from salt

    Answer:

    1. a) A process known as centrifugation is used to separate butter from curd. The process is governed by the principle of density.
    2. b) We can use the simple evaporation technique to separate salt from seawater. Distillation causes water to evaporate, leaving solid salt behind, hence the production of salt.
    3. c) Sublimation can be used to separate camphor from salt, as during the phase change, camphor does not undergo a liquid phase.
    1. What types of mixtures are separated by the technique of crystallization?

    Answer:

    The technique of crystallisation is used to separate solids from a liquid ,. It is linked to precipitation, but in this technique, the precipitate is achieved in a crystal form which exhibits extremely high levels of purity. The principle of crystallisation can be applied to purify impure substances.

    Exercise-2.4 Page: 24

    1. Classify the following as physical or chemical changes:

    Answer:

    The following is the classification into physical and chemical change:

    Difference between Mixtures and Compounds

    Compound Mixture
    Formed by chemically combining two or more elements. Formed by physically mixing two or more substances.
    Pure substance. Impure substance.
    Fixed composition. Variable composition.
    Always homogeneous. Can be homogeneous or heterogeneous.
    New substance formed with different properties. No new substance formed; properties remain individual.

    Difference between Homogeneous and Heterogeneous Mixtures

    Homogeneous Mixture Heterogeneous Mixture
    Particles are uniformly distributed. Particles can be distinguished easily.
    Uniform composition. Irregular composition.
    No visible boundaries. Visible boundaries between components.

    Examples of Physical and Chemical Changes

    Physical Change Chemical Change
    • Cutting trees
    • Boiling water
    • Melting butter
    • Making fruit salad
    • Dissolving salt in water
    • Rusting of iron
    • Electrolysis of water
    • Burning wood or paper

    Pure Substances and Mixtures

    Pure Substance Mixture
    Water Soil
    Salt Salad
    Iron Air
    Diamond Steel

    Exercise Page: 28

    1. Which separation techniques will you apply for the separation of the following?

    (a) Sodium chloride from its , in water.

    (b) Ammonium chloride from a mixture containing sodium chloride and ammonium chloride.

    (c) Small pieces of metal in the engine oil of a car.

    (d) Different pigments from an extract of flower petals.

    (e) Butter from curd.

    (f) Oil from water.

    (g) Tea leaves from tea.

    (h) Iron pins from sand.

    (i) Wheat grains from husk.

    (j) Fine mud particles suspended in water.

    Answer:

     (a) In water, sodium chloride in its , can be separated through the process of Evaporation.

    (b) The technique of sublimation is apt as Ammonium chloride supports Sublimation.

    (c) Tiny chunks of metal pieces in the engine oil of a car can be manually filtered.

    (d) Chromatography can be used for the fine segregation of various pigments from an extract of flower petals.

    (e) The technique of centrifugation can be applied to separate butter from curd. It is based on the concept of difference in density.

    (f) To separate oil from water, which are two immiscible liquids which vary in their densities, using a funnel can be an effective method.

    (g) Tea leaves can be manually separated from tea using simple filtration methods.

    (h) Iron pins can be separated from sand either manually or with the use of magnets as the pins exhibit strong magnetic quality, which can be a key characteristic taken into consideration.

    (i) The differentiating property between husk and wheat is that there is a difference in their mass. If treated with a small amount of wind energy, a remarkable variation in the moving distance is noticed. Hence, to separate them, the sedimentation/winnowing procedure can be applied.

    (j) Due to the property of water, sand or fine mud particles tends to sink in the bottom as it is denser provided they are undisturbed. Through the process of sedimentation/decantation, water can be separated from fine mud particles, as the technique is established on obtaining clear water by tilting it out.

    1. Write the steps you would use for making tea. Use the words solvent, solute, dissolve, soluble, insoluble, filtrate, and residue.

    Answer:

    (a) Into a vessel, add a cup of milk, which is the solvent, and supply it with heat.

    (b) Add tea powder or tea leaves to the boiling milk, which acts as a solute. Continue to heat.

    (c) The solute, i.e., the tea powder, remains insoluble in the milk, which can be observed while it is still boiling.

    (d) At this stage, add some sugar to the boiling , while stirring.

    (e) Sugar is a solute but is soluble in the solvent.

    (f) Continuous stirring causes the sugar to dissolve completely in the tea ,reaching saturation.

    (g) Once the raw smell of tea leaves vanishes and the tea , is boiled enough, take the , off the heat, filter or strain it to separate the tea powder and the tea ,. The insoluble tea powder remains as a residue while the solute (sugar) and the solvent (essence milk ,) strain through the filter medium, which is collected as the filtrate.

    1. Pragya tested the solubility of three different substances at different temperatures and collected the data as given below (results are given in the following table, as grams of a substance dissolved in 100 grams of water to form a saturated ,).

    Substance dissolved

    Temperature in K

    283

    293

    313

    333

    353

    Solubility

    Potassium nitrate

    21

    32

    62

    106

    167

    Sodium chloride

    36

    36

    36

    37

    37

    Potassium chloride

    35

    35

    40

    46

    54

    Ammonium chloride

    24

    37

    41

    55

    66

    (a) What mass of potassium nitrate would be needed to produce a saturated solution of

    potassium nitrate in 50 grams of water at 313K?

    (b) Pragya makes a saturated , of potassium chloride in water at 353 K and leaves the

    , to cool at room temperature. What would she observe as the , cools? Explain.

    (c) Find the solubility of each salt at 293 K. Which salt has the highest solubility at this

    temperature?

    (d) What is the effect of change of temperature on the solubility of a salt?

    Answer:

     (a) Given: Mass of potassium nitrate required to produce a saturated solution in 100 g of water at 313 K = 62g

    To find: Mass of potassium nitrate required to produce a saturated solution in 50 g of water =?

    Required amount = 62 x 50/100 = 31. Hence, 31 g of potassium nitrate is required.

    (b) The solubility of potassium chloride in water is decreased when a saturated , of potassium chloride loses heat at 353 K. Consequently, Pragya would observe crystals of potassium chloride, which would have surpassed its solubility at low temperatures.

    (c) As per the given data, that is

    Solubility of potassium nitrate at 293K = 32 g

    Solubility of sodium chloride at 293K = 36 g

    Solubility of potassium chloride at 293K = 35 g

    Solubility of ammonium chloride at 293K = 37g

    We can observe from this data that ammonium chloride has the highest solubility at 293K.

    (d) Effect of change of temperature on the solubility of salts:

    The table clearly depicts that the solubility of the salt is dependent upon the temperature and increases with an increase in temperature. With this, we can infer that when a salt arrives at its saturation point at a specific temperature, there is a propensity to dissolve more salt through an increase in the temperature of the

    1. Explain the following, giving examples.

    (a) Saturated solution

    (b) Pure substance

    (c) Colloid

    (d) Suspension

    Answer:

     (a) Saturated ,: It is the state in a , at a specific temperature when a solvent is no more soluble without an increase in temperature. Example: Excess carbon leaves off as bubbles from a carbonated water , saturated with carbon.

    (b) Pure substance: A substance is said to be pure when it comprises only one kind of molecule, atom or compound without adulteration with any other substance or any divergence in the structural arrangement. Examples: Sulphur, diamonds etc.

    (c) Colloid: A Colloid is an intermediate between , and suspension. It has particles of various sizes that range between 2 to 1000 nanometers. Colloids can be distinguished from ,s using the Tyndall effect. Tyndall effect is defined as the scattering of light (light beam) through a colloidal ,. Examples: Milk and gelatin.

    (d) Suspension: It is a heterogeneous mixture that comprises solute particles that are insoluble but are suspended in the medium. These particles that are suspended are not microscopic but visible to bare eyes and are large enough (usually larger than a micrometre) to undergo sedimentation.

    1. Classify each of the following as a homogeneous or heterogeneous mixture.

    soda water, wood, air, soil, vinegar, filtered tea.

    Answer:

    The following is the classification of the given substances into homogenous and heterogenous mixtures.

    Homogenous mixture

    Heterogeneous mixture

    Soda water

    wood

    vinegar

    soil

    Filtered tea

    Air

    1. How would you confirm that a colourless liquid given to you is pure water?

    Answer:

    We can confirm if a colourless liquid is pure by setting it to boil. If it boils at 100°C, it is said to be pure. But if there is a decrease or increase in the boiling point, we infer that water has added impurities, hence not pure.

    1. Which of the following materials fall into the category of “pure substance”?

    (a) Ice

    (b) Milk

    (c) Iron

    (d) Hydrochloric acid

    (e) Calcium oxide

    (f) Mercury

    (g) Brick

    (e) Wood

    (f) Air.

    Answer:

    Following substances from the above-mentioned list are pure substances:

    1. Identify the, solutions among the following mixtures.

    (a) Soil

    (b) Sea water

    (c) Air

    (d) Coal

    (e) Soda water

    Answer:

    The following are the solutions from the above-mentioned list of mixtures:

    1. Which of the following will show the “Tyndall effect”?

    (a) Salt ,

    (b) Milk

    (c) Copper sulphate ,

    (d) Starch ,

    Answer:

    Tyndall effect is exhibited by only milk and starch , from the above-mentioned list of ,s.

    1. Classify the following into elements, compounds and mixtures.

    (a) Sodium (b) Soil (c) Sugar (d) Silver (e) Calcium carbonate (f) Tin (g) Silicon (h) Coal (i) Air (j) Soap (k) Methane

    (l) Carbon dioxide (m) Blood

    Answer:

    Elements

    Compounds

    Mixture

    Sodium

    Calcium carbonate

    Soil

    Silver

    Carbon dioxide

    Sugar ,

    Tin

    Methane

    Coal

    Silicon

    Air

    Blood

    Soap

    1. Which of the following are chemical changes?

    (a) Growth of a plant 

    (b) Rusting of iron

    (c) Mixing of iron filings and sand 

    (d) Cooking of food

    (e) Digestion of food 

    (f) Freezing of water

    (g) Burning of candle

    Answer:

     Out of the given list, the following are chemical changes:

    Growth of a plant, rusting of iron, cooking of food, digestion of food and burning of candles.