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Acids, Bases, and Salts

Take the Quiz on Acids, Bases and Salts

Classification of Matter

Matter is classified based on different factors. One important classification is based on atomic composition, according to which matter exists as solids, liquids, and gases. Another classification depends on the density and arrangement of atoms or molecules in a substance. Matter is also classified based on hydrogen ion concentration into acids, bases, and salts.

In our everyday experiences, we frequently come across different forms of matter. Sour substances such as lemon juice and vinegar indicate the presence of acids. Bitter and slippery substances like baking soda and soap show the presence of bases.

Acids are substances that are sour in taste and turn blue litmus paper red. Acids are commonly found in natural and household substances. Citrus fruits contain citric acid, curd contains lactic acid, tamarind contains tartaric acid, and vinegar contains acetic acid.

Bases are substances that are bitter in taste, slippery to touch, and turn red litmus paper blue. Lime water contains calcium hydroxide, baking soda contains sodium bicarbonate, and many cleaning agents and antacids are basic in nature. When bases dissolve in water, they are called alkalis.

Salts are substances that are usually neutral in nature and are formed as a result of reactions between acids and bases. Salts are widely used in cooking, food preservation, and in the manufacture of many industrial products.

To identify acids and bases safely, scientists use special substances called indicators. Litmus turns red in acids and blue in bases. Turmeric remains yellow in acidic solutions but turns reddish-brown in basic solutions. China rose indicator becomes pink in acids and greenish in bases.

Acids and bases have great practical importance in daily life. Antacids are used to relieve stomach acidity by neutralizing excess acid. In agriculture, lime is added to acidic soil to make it suitable for farming. Baking soda is commonly used for cooking and cleaning purposes. Acids and bases are also essential ingredients in many cleaning agents and industrial solutions.

🔹 Arrhenius’ Theory of Acids and Bases

The Arrhenius Theory, proposed by Swedish scientist Svante Arrhenius in 1884, was one of the earliest models to explain acid-base behavior in aqueous solutions.

Examples:

Neutralization reaction:
H⁺ + OH⁻ → H₂O

Limitations of Arrhenius Theory:

Despite these limitations, the Arrhenius theory laid the foundation for understanding many simple acid-base reactions in water.


🔹 Brønsted–Lowry Theory of Acids and Bases

Developed independently by Johannes Brønsted and Thomas Lowry in 1923, this theory extends the concept of acids and bases beyond water-based reactions.

Example: Reaction between HCl and NH₃:
HCl + NH₃ → NH₄⁺ + Cl⁻

Conjugate Acid–Base Pairs:

Additional Key Concept:

This theory can explain acid-base behavior in gas phases, non-aqueous solutions, and reversible reactions, making it more versatile and broadly applicable than the Arrhenius theory.


🔍 Acid–Base Indicators

Acid–base indicators are substances that change their color depending on whether they are in an acidic or basic solution. Since tasting or touching unknown substances is unsafe, indicators offer a quick and safe way to test for acids or bases. Indicators react with hydrogen ions (H⁺) or hydroxide ions (OH⁻) to produce a visible color change.

🟢 Types of Indicators:

1. Natural Indicators

These are indicators extracted from natural sources like plants. They are commonly used in household and educational settings.

2. Synthetic Indicators

These are man-made chemical compounds used mostly in labs for titrations and precise analysis.

3. Universal Indicator

universal indicator is a mixture of several indicators that provides a wide range of color changes across the entire pH scale (0 to 14). It can give more specific information about how acidic or basic a solution is.

Understanding indicators helps us detect the nature of substances safely, both in labs and at home. They play a key role in chemical analysis, agriculture, medicine, and industry.


Acids and Bases – Their Reaction with Indicators

🔹 Litmus Reaction

Litmus Reaction

Litmus is a natural indicator extracted from lichens. It is available in both solution and paper form (red and blue). It reacts visibly with acids and bases:

Litmus is widely used in school labs, industries, agriculture, and environmental testing due to its quick, safe, and clear results.

🔸 Reaction with Methyl Orange

Methyl orange is a synthetic indicator used mainly in titrations. It shows sharp and distinct color changes:

Because of its sharp transition, methyl orange is perfect for identifying the end point in strong acid–weak base titrations.

🔺 Reaction with Phenolphthalein

Phenolphthalein is another common laboratory indicator, especially used in titrations involving strong bases:

The sudden color change makes phenolphthalein very effective in acid-base titration experiments.

📘 Summary Table of Indicators

📘 Summary Table of Indicators

Indicator Acid Base Neutral
Litmus Blue → Red Red → Blue No change
Methyl Orange Red Yellow Orange
Phenolphthalein Colorless Pink Colorless

Dilution of acid bases

Dilution is the process of reducing the concentration of a solution by adding more solvent (usually water) to it. It is a highly exothermic process. To dilute acid, the acid must be added to water and not the other way round.


Strength of acid, base and salts

The strength of acids and bases refers to their degree of ionization or dissociation in water, which directly affects their reactivity and the concentration of hydrogen (H⁺) or hydroxide (OH⁻) ions they produce. A strong acid is one that completely ionizes in an aqueous solution, releasing a large number of H⁺ ions. Examples include hydrochloric acid (HCl), sulfuric acid (H₂SO₄), and nitric acid (HNO₃). In contrast, a weak acid only partially ionizes in water and releases fewer H⁺ ions—examples include acetic acid (CH₃COOH) and citric acid. Similarly, a strong base like sodium hydroxide (NaOH) or potassium hydroxide (KOH) completely dissociates to release OH⁻ ions, whereas a weak base like ammonium hydroxide (NH₄OH) or magnesium hydroxide (Mg(OH)₂) only partially dissociates. The strength of these substances affects their ability to participate in chemical reactions, their corrosiveness, and their behavior in neutralization reactions. On the other hand, salts, which are formed by the neutralization of acids and bases, can be neutral, acidic, or basic depending on the strength of the acid and base that produced them. For example, the salt sodium chloride (NaCl) formed from a strong acid (HCl) and strong base (NaOH) is neutral. However, ammonium chloride (NH₄Cl), formed from a strong acid and weak base, results in an acidic salt, while sodium carbonate (Na₂CO₃), formed from a strong base and weak acid, is a basic salt. Thus, the strength of acids, bases, and the nature of the salt formed plays a crucial role in determining the pH, reactivity, and behavior of solutions in chemical and biological systems.


pH Scale

The pH scale ranges from 0 to 14 and helps determine how acidic or basic a solution is. A value below 7 indicates acidity, 7 is neutral, and above 7 is basic.

pH Scale

pH in Our Daily Life

The concept of pH, which measures the acidity or basicity of a solution on a scale from 0 to 14, plays a vital role in everyday life. A proper balance of pH is essential for biological, chemical, agricultural, and environmental processes.

In the human body, the stomach secretes hydrochloric acid (pH around 1.5 to 3.5) to aid digestion and kill harmful bacteria. Excess acid causes acidity or heartburn, which is treated using antacids that neutralize the acid.

In oral care, maintaining mouth pH is important because a drop below pH 5.5 can cause tooth enamel erosion and cavities. Hence, toothpaste is slightly basic.

In agriculture, soil pH affects nutrient availability. Acidic soils are treated with lime. Water bodies are monitored for pH to protect aquatic life.

In the food industry, pH controls taste and preservation, such as the sourness of curd or fizz in soft drinks. Household cleaners are also designed based on pH to remove grease and stains.


Acid–Base Reactions

Neutralization

A neutralization reaction occurs when an acid reacts with a base to form salt and water. Acid + Base → Salt + Water + Heat

Example: HCl + NaOH → NaCl + H₂O


Reaction of Acids with Metals

Acids react with metals to produce salt and hydrogen gas.

Example: 2HCl + Mg → MgCl₂ + H₂↑


Reaction of Bases with Metals

When a base reacts with certain metals like zinc, hydrogen gas is released and complex salts are formed.

Example: 2NaOH + Zn → Na₂ZnO₂ + H₂↑


Reaction of Acids with Metal Carbonates and Bicarbonates

Acids react with metal carbonates or bicarbonates to produce salt, water, and carbon dioxide.

Example: 2HCl + CaCO₃ → CaCl₂ + H₂O + CO₂


Reaction of Non-Metal Oxides with Bases

Non-metal oxides are acidic in nature and react with bases to form salt and water.

Example: 2NaOH + CO₂ → Na₂CO₃ + H₂O


Reaction of Acids and Bases in Water

Acids and bases dissociate into ions in water and conduct electricity.

NaOH → Na⁺ + OH⁻
HCl → H⁺ + Cl⁻


Difference Between a Base and an Alkali

Base Alkali
A base neutralizes an acid. An alkali is a base soluble in water.
May be soluble or insoluble. Always soluble in water.
Example: CuO, ZnO Example: NaOH, KOH

Preparation of Acids

Acids can be prepared from non-metal oxides reacting with water.

Example: SO₂ + H₂O → H₂SO₃

Hydrogen reacts with non-metals to form acids. Example: H₂ + Cl₂ → 2HCl


Preparation of Bases

Bases are prepared by reacting metal oxides with water. Example: CaO + H₂O → Ca(OH)₂

Reactive metals with water also form bases. Example: 2Na + 2H₂O → 2NaOH + H₂↑

Electrolysis of brine produces sodium hydroxide (Chlor-alkali process).


Salts

Preparation of Salts

Salts are formed by the neutralization of acids and bases. Example: NaCl (common salt)

Family of Salts

Salts derived from the same acid or base form a family of salts. Examples include chlorides, sulphates, nitrates, and carbonates.

Naming of Salts

Salts are named after the anion of the acid, such as chlorides (NaCl), sulphates (Na₂SO₄), nitrates (KNO₃), and carbonates (Na₂CO₃).

pH of Salts

A salt formed by a strong acid and a strong base will be neutral with pH = almost 7 . A salt of a weak acid and a strong base will be alkaline in nature with pH > 7. A salt of a strong acid and a weak base will be acidic in nature. pH < 7. The pH of a salt of a weak acid and a weak base is determined by conducting a pH test.

Common Salt

Common salt, also known as sodium chloride (NaCl), is a white crystalline substance widely used in cooking and food preservation. It is made up of sodium and chloride ions and is an essential mineral for the human body, helping to regulate fluids and nerve functions. Common salt is mainly obtained from sea water through evaporation or mined from rock salt deposits. Apart from its use in food, it serves as a raw material for producing important chemicals like sodium hydroxide, baking soda, and hydrochloric acid. It also finds use in industries, water softening, and de-icing roads in cold climates.

Chemicals Prepared from Common Salt:

Common salt (Sodium chloride – NaCl) is not just used in cooking; it is also a raw material for making many important industrial chemicals.Some important compounds of common salts are as follows:

Sodium Hydroxide (NaOH) is prepared by the electrolysis of brine (brine = solution of NaCl in water). The equation can be written as 2NaCl + 2H₂O → 2NaOH + Cl₂ + H₂. It is used in making soap, paper, and cleaning agents.Chlorine (Cl₂) is obtained during electrolysis of brine. It is used for disinfecting water, making PVC plastic, and bleaches.Hydrogen (H₂) is a by-product of the electrolysis of brine. It is used as fuel, band a catalyst for hydrogenation of oils.Bleaching Powder (Ca(OCl)Cl) : It is prepared by reacting chlorine with slaked lime (Ca(OH)₂). The equation for this is, Cl₂ + Ca(OH)₂ → Ca(OCl)Cl + H₂O. Bleaching powder is used as a disinfectant, bleaching agent for fabrics and paper. Baking Soda (NaHCO₃) : Made through Solvay process. Where, sodium chloride + ammonia + CO₂ + water (Solvay process). It is useful in baking, as an antacid, and fire extinguisher. Washing Soda (Na₂CO₃·10H₂O) : Made when baking soda is heated and re-crystallized. It is useful for Softening hard water, glass and soap manufacturing. Hydrochloric Acid (HCl): prepared by dissolving hydrogen chloride gas in water. It is used in cleaning metals, making medicines .

Crystallization of Salts

Crystallization is a process used to obtain pure solid crystals from a solution. It is a physical change commonly used in chemistry labs and industries to purify substances. Crystallization involves the formation of solid crystals from a homogeneous solution. The basic steps include:

LBA Solutions

Learning Points

  1. Physical properties of acids, bases
  2. Chemical properties of acids, bases
  3. How strong are solutions of acids and bases
  4. Importance of pH in daily life
  5. More about salts
  6. Uses of salts

Question Paper Pattern

Sl. No

Type of Questions

No. of Questions

Marks

Percentage

1

Easy

16

35

30%

2

Average

32

59

50%

3

Difficult

19

23

20%

I. Multiple Choice Questions (1 Mark each)

  1. The chemical equation that represents a neutralization reaction is:
    A) BaCl₂ + H₂SO₄ → BaSO₄ + 2HCl
    B) MnO₂ + 4HCl → MnCl₂ + 2H₂O + Cl₂
    C) 2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O
    D) AgNO₃ + HCl → AgCl + HNO₃
  2. As the pH value of a neutral solution increases:
    A) Basic property decreases and OH⁻ ions increase
    B) Acidic property increases and H⁺ ions decrease
    C) Basic property increases and OH⁻ ions increase
    D) Acidic property decreases and H⁺ ions increase
  3. A compound that reacts with both acids and bases to produce salts and water is:
    A) Aluminium oxide
    B) Copper oxide
    C) Iron oxide
    D) Sodium oxide
  4. The gas liberated when sodium carbonate reacts with dilute hydrochloric acid is:
    A) Carbon dioxide
    B) Nitrogen dioxide
    C) Hydrogen
    D) Chlorine
  5. The substance that turns blue litmus paper red is:
    A) Lime water
    B) Pure water
    C) Sodium hydroxide solution
    D) Gastric juice
  6. An acid present in the stinging hair of nettle plant leaves is:
    A) Methanoic acid
    B) Oxalic acid
    C) Citric acid
    D) Lactic acid
  7. The compound used to remove permanent hardness of water is:
    A) Sodium carbonate
    B) Sodium hydroxide
    C) Sodium hydrogen carbonate
    D) Sodium chloride
  8. The pH value range of an acid is:
    A) 0–7
    B) 2–12
    C) 7–14
    D) 12–14
  9. As the number of hydrogen ions increases in a solution, it:
    A) Becomes neutral
    B) Increases acidity
    C) Increases basicity
    D) Reduces acidity
  10. Gas released when dilute sulphuric acid reacts with lead is:
    A) Oxygen
    B) Nitrogen
    C) Hydrogen
    D) Carbon
  11. The product obtained when an acid reacts with a metal is:
    A) Metal oxide + water
    B) Salt + water
    C) Metal oxide + hydrogen gas
    D) Salt + hydrogen gas
  12. The molecular formula of lime water is:
    A) CaO
    B) Ca(OH)₂
    C) CaCO₃
    D) CO₂
  13. When hydrochloric acid is added to copper oxide, the solution turns blue-green due to:
    A) Copper oxide
    B) Water
    C) Copper hydroxide
    D) Copper chloride
  14. Acid should be added to water, not water to acid, because it is:
    A)
    Exothermic and may explode
    B) Endothermic and may explode
    C) Does not mix
    D) Mixes very slowly

Key Answers

I. Multiple Choice Questions

  1. (C) 2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O
  2. (C) Basic property increases and number of OH⁻ ions increases
  3. (A) Aluminium oxide
  4. (A) Carbon dioxide
  5. (D) Gastric juice
  6. (A) Methanoic acid
  7. (A) Sodium carbonate
  8. (A) 0 – 7
  9. (D) Reduces acidity
  10. (C) Hydrogen
  11. (C) Metal oxide and hydrogen gas
  12. (B) Ca(OH)₂
  13. (C) Copper hydroxide
  14. (A) Exothermic and may explode

II. Answer the Following (1 Mark each)

  1. What is a neutralization reaction?
  2. Why should plaster of Paris be stored in a moisture-proof container?
  3. What are amphoteric oxides?
  4. Can detergents be used to detect permanent hardness of water? Give reason.
  5. Name the ions responsible for acidic and basic nature of substances.
  6. Write any two uses of washing soda.
  7. 1 ml of acetic acid is mixed with 1 ml of sodium hydroxide solution. Determine the nature of the salt formed with reason.
  8. How is concentrated acid diluted?
  9. How do you detect acid using litmus paper?
  10. What is an acid?
  11. Write a chemical equation for the reaction of a metal with a base.
  12. What is the reaction product when air is blown into lime water?
  13. Which gas is released when acids react with metal carbonate and metal hydrogen carbonate?
  14. Why is a metal oxide called a basic oxide?
  15. Why is a non-metal oxide called an acidic oxide?
  16. What are bases?
  17. What ion is formed when an acid dissolves in water?
  18. What happens as the number of hydroxide ions increases in a solution?
  19. What is the pH value of acid rain?
  20. What is the chemical name of baking powder?
  21. Write the chemical equation for the preparation of baking powder.
  22. What is baking powder?
  23. Give the molecular formula and chemical name of washing soda.
  24. Which salt is used in fire extinguishers?
  25. Why does baking soda swell when mixed with bread dough?

1 Mark Key Answers

  1. The reaction between an acid and a base producing salt and water is called neutralisation reaction.
  2. Amphoteric oxides are metallic oxides that show both acidic and basic behaviour.
  3. Uses of Plaster of Paris (any two):
    Supporting fractured bones
    • Making toys
    • Decorative materials
    • Making smooth surfaces
  4. Acidic nature: H⁺ / H₃O⁺ ions
  5. Uses of washing soda:
    i) Glass, soap and paper industries
    ii) Manufacture of sodium compounds like borax
  6. It is a basic salt because sodium hydroxide is a strong base.
  7. By adding acid slowly to water with constant stirring.
  8. Blue litmus turns red in acid; red litmus shows no change.
  9. A solution with pH value 0–7 is called an acid.
  10. 2NaOH + Zn → Na₂ZnO₂ + H₂
  11. Calcium carbonate (CaCO₃)
  12. Carbon dioxide (CO₂)
  13. Metal oxides react with acids to form salt and water, hence called basic oxides.
  14. Non-metal oxides react like acids and form salt and water.
  15. Bases contain hydroxide (OH) ions.
  16. Hydronium ion (HO)
  17. Basicity and pH value increase.
  18. Less than 5
  19. Calcium oxychloride
  20. Ca(OH)₂ + Cl₂ → CaOCl₂ + H₂O
  21. Baking powder is an edible mixture of baking soda and tartaric acid.
  22. NaHCO₃ — Sodium hydrogen carbonate
  23. NaHCO₃ — Sodium hydrogen carbonate
  24. Baking soda produces CO₂ gas when reacting with water.

III. Answer the Following (2 Marks each)

  1. Give scientific reason: While diluting an acid, the acid should be added to water.
  2. Why do agricultural scientists recommend adding lime powder to agricultural fields?
  3. pH values of solutions A, B and C are 5, 6 and 7 respectively. Which is most acidic and why?
  4. State the properties of acids.
  5. State the properties of bases.
  6. Using only red litmus paper, how will you identify distilled water, acidic and basic solutions?
  7. Why do HCl and HNO₃ show acidic properties in aqueous solutions but alcohol and glucose do not?
  8. Why does rainwater conduct electricity but distilled water does not?
  9. Fresh milk has pH 6. How does its pH change as it curdles? Explain.
  10. A milkman adds a small amount of baking soda to fresh milk:
    a) Why does he make it slightly alkaline?
    b) Why does the milk take longer to curdle?

Key Answers- 2 Marks

  1. Adding water to acid releases heat suddenly and may cause splashing or break the container.
  1. Solution A is most acidic due to higher H⁺
  2. Properties of acids:
    Sour taste
    • Turn blue litmus red
    • Contain H⁺ ions
    • Conduct electricity
  3. Properties of bases:
    Bitter taste
    • Turn red litmus blue
    • Contain OH⁻ ions
    • Poor conductors
  1. • No change → Distilled water
    • Red → Blue → Base
    • Blue → Red → Acid
  1. HCl and HNO₃ produce H⁺ ions in water; glucose and alcohol do not.
  2. Rainwater contains ions; distilled water has no ions.
  3. pH decreases due to formation of lactic acid.
  1. a) To increase shelf life
    b) Alkaline milk curdles slowly

IV. Answer the Following (3 Marks each)

  1. Draw the apparatus to show reaction of zinc with dilute sulphuric acid and testing hydrogen gas.
  2. Name the gas released when acid reacts with metal carbonate. Write the equation and colour of precipitate.
  3. Explain colour change of litmus after electrolysis of sodium chloride solution. Mention two uses of the product.
  4. What is a strong acid? Explain tooth decay and its prevention.
  5. Write molecular formula and two uses of:
    a) Bleaching powder
    b) Plaster of Paris
  6. What is a neutralization reaction? Give an example.
  7. What is the common name of CaSO₄½H₂O?
  8. Differentiate concentrated and weak acids. Mention precautions.
  9. Name the salts used for:
    a) Removing permanent hardness of water
    b) Purifying drinking water
    c) Supporting fractured bones
  10. Given pH values of four solutions:
    a) Classify them as acidic or basic
    b) Name the antacid used for excess stomach acid
  11. Explain litmus changes in brine and its electrolysed product.
  12. Observe the pH table and answer questions.
  13. Name the acid present in:
    i) Curd
    ii) Gastric juice
  14. Solutions A, B, C and D have pH 2, 6, 8 and 13 respectively:
    i) Which has more H⁺ and OH⁻ ions?
    ii) Which solutions form neutral salts?

IV. Three-Mark key Answers

  1. Reaction of zinc granules with sulphuric acid
  2. Gas: Carbon dioxide
    Ca(OH)₂ + CO₂ → CaCO₃ + H₂O
    White precipitate formed
  3. Product: Sodium hydroxide (NaOH)
    Uses:
    Soap and detergent making
    • Paper industry
  4. Strong acids produce more H⁺
    Tooth decay is caused by acids produced by bacteria.
    Prevented by basic toothpaste.
  1. a) Bleaching powder (CaOCl) – bleaching, disinfecting
    b) Plaster of Paris (CaSO
    ·½HO) – toys, decoration
  1. Neutralisation: NaOH + HCl → NaCl + H₂O
  2. Plaster of Paris / Calcium sulphate hemihydrate
  1. • Concentrated acids contain less water
    • Weak acids produce fewer H⁺ ions
    • Always add acid to water slowly
  1. a) Sodium hydroxide
    b) Bleaching powder
    c) Plaster of Paris
  1. a) Acidic – e, h
    Basic – g
    b) Milk of magnesia (Mg(OH)₂)
  1. • Brine: No change (neutral)
    • Electrolysed product: Red litmus → Blue (basic)
  1. i) P – mild base, antacid
    ii) Q and S – strong base + strong acid
  1. i) Curd – Lactic acid
    ii) Gastric juice – Hydrochloric acid

V. Answer the Following (4 Marks each)

  1. Name the products of the chlor-alkali process and give one use of each.
  2. Using NaOH, Ca(OH)₂, H₂ and Cl₂, explain preparation of bleaching powder with one use.
  1. How do you identify a basic solution using blue litmus paper?
  2. When does a farmer treat soil with slaked lime?
  3.  Write differences between acids and bases.

Four Marks- key Answers

  1. Name the products of the chlor-alkali process and give one use of each.

Answer:The products of the chlor-alkali process are:
• Sodium hydroxide – Used in the manufacture of soaps and detergents.
• Chlorine – Used for disinfecting drinking water.
• Hydrogen – Used as a fuel.

  1. Using NaOH, Ca(OH), H and Cl, explain preparation of bleaching powder with one use.

Bleaching powder is prepared by passing chlorine gas over dry slaked lime.
Chlorine gas is obtained during the chlor-alkali process in which sodium hydroxide and hydrogen gas are also produced.

Reaction:Calcium hydroxide + Chlorine → Bleaching powder + Water

One use of bleaching powder:• It is used for disinfecting drinking water.

  1. How do you identify a basic solution using blue litmus paper?

A basic solution does not change the colour of blue litmus paper. The blue litmus paper remains blue.

  1. When does a farmer treat soil with slaked lime?

A farmer treats the soil with slaked lime when the soil is acidic. Slaked lime neutralizes the acidity of the soil and improves fertility.

  1. Write differences between acids and bases.

Acids:
• Sour in taste
• Turn blue litmus paper red
• Produce hydrogen ions in solution
• Example: Hydrochloric acid, Sulphuric acid

Bases:
• Bitter in taste
• Turn red litmus paper blue
• Produce hydroxide ions in solution
• Example: Sodium hydroxide, Calcium hydroxide